Crystal structure of monoprotonated Ni(II) nitrilotriacetate tetrahydrate [Articol]
dc.contributor.author | Petrenko, Peter A. | |
dc.contributor.author | Gdaniec, Maria | |
dc.contributor.author | Simonov, Iurie | |
dc.contributor.author | Stăvilă, Vitalie | |
dc.contributor.author | Gulea, Aurelian | |
dc.date.accessioned | 2023-10-24T13:49:23Z | |
dc.date.available | 2023-10-24T13:49:23Z | |
dc.date.issued | 2004 | |
dc.description.abstract | A Ni(II) complex of the composition Ni(HNta)·4H 2O (I) was synthesized. Its structure was found to consist of neutral mononuclear [Ni(HNta)(H 2O) 3] complexes and crystallization water molecules. The Ni atom has octahedral surrounding and is coordinated to tridentate-chelate HNta 2- ligand through the N atom and O atoms of two deprotonated acetate groups and through the O atoms of three water molecules. The structure of I was compared with those of the Zn(HNta)·4H 2O and Co(HNta)·4H 2O complexes isostructural to I. Thermogravimetric method showed that the decomposition of compound I occurs through several successive stages of dehydration, deaquation, decarboxylation, and the formation of inorganic residue. | en |
dc.description.sponsorship | 12.839.08.05F Probleme de studiu local şi global al singularităţilor cîmpurilor vectoriale polinomiale | en |
dc.identifier.citation | PETRENKO, Peter A., GDANIEC, Maria, SIMONOV, Iurie , STĂVILĂ, Vitalie, GULEA, Aurelian. Crystal structure of monoprotonated Ni(II) nitrilotriacetate tetrahydrate. În: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2004, vol. 30, pp. 813-817. ISSN 1070-3284 | en |
dc.identifier.issn | 1070-3284 | |
dc.identifier.uri | https://msuir.usm.md/handle/123456789/11450 | |
dc.identifier.uri | https://doi.org/10.1023/B:RUCO.0000047470.68177.4a | |
dc.language.iso | en | en |
dc.subject | EMTREE drug terms acetic acid derivative | en |
dc.subject | cobalt derivative | en |
dc.subject | nickel | en |
dc.subject | nitrilotriacetic acid | en |
dc.subject | Nitrogen | en |
dc.subject | oxygen | en |
dc.subject | water | en |
dc.subject | zinc derivative EMTREE medical terms article | en |
dc.subject | Chelation | en |
dc.subject | Chemical composition | en |
dc.subject | chemical structure | en |
dc.subject | comparative study | en |
dc.subject | crystal structure | en |
dc.subject | crystallization | en |
dc.subject | decarboxylation | en |
dc.subject | decomposition | en |
dc.subject | dehydration | en |
dc.subject | proton transport | en |
dc.subject | synthesis | en |
dc.subject | thermogravimetry | en |
dc.title | Crystal structure of monoprotonated Ni(II) nitrilotriacetate tetrahydrate [Articol] | en |
dc.type | Article | en |