Crystal structure of monoprotonated Ni(II) nitrilotriacetate tetrahydrate [Articol]

dc.contributor.authorPetrenko, Peter A.
dc.contributor.authorGdaniec, Maria
dc.contributor.authorSimonov, Iurie
dc.contributor.authorStăvilă, Vitalie
dc.contributor.authorGulea, Aurelian
dc.date.accessioned2023-10-24T13:49:23Z
dc.date.available2023-10-24T13:49:23Z
dc.date.issued2004
dc.description.abstractA Ni(II) complex of the composition Ni(HNta)·4H 2O (I) was synthesized. Its structure was found to consist of neutral mononuclear [Ni(HNta)(H 2O) 3] complexes and crystallization water molecules. The Ni atom has octahedral surrounding and is coordinated to tridentate-chelate HNta 2- ligand through the N atom and O atoms of two deprotonated acetate groups and through the O atoms of three water molecules. The structure of I was compared with those of the Zn(HNta)·4H 2O and Co(HNta)·4H 2O complexes isostructural to I. Thermogravimetric method showed that the decomposition of compound I occurs through several successive stages of dehydration, deaquation, decarboxylation, and the formation of inorganic residue.en
dc.description.sponsorship12.839.08.05F Probleme de studiu local şi global al singularităţilor cîmpurilor vectoriale polinomialeen
dc.identifier.citationPETRENKO, Peter A., GDANIEC, Maria, SIMONOV, Iurie , STĂVILĂ, Vitalie, GULEA, Aurelian. Crystal structure of monoprotonated Ni(II) nitrilotriacetate tetrahydrate. În: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2004, vol. 30, pp. 813-817. ISSN 1070-3284en
dc.identifier.issn1070-3284
dc.identifier.urihttps://msuir.usm.md/handle/123456789/11450
dc.identifier.urihttps://doi.org/10.1023/B:RUCO.0000047470.68177.4a
dc.language.isoenen
dc.subjectEMTREE drug terms acetic acid derivativeen
dc.subjectcobalt derivativeen
dc.subjectnickelen
dc.subjectnitrilotriacetic aciden
dc.subjectNitrogenen
dc.subjectoxygenen
dc.subjectwateren
dc.subjectzinc derivative EMTREE medical terms articleen
dc.subjectChelationen
dc.subjectChemical compositionen
dc.subjectchemical structureen
dc.subjectcomparative studyen
dc.subjectcrystal structureen
dc.subjectcrystallizationen
dc.subjectdecarboxylationen
dc.subjectdecompositionen
dc.subjectdehydrationen
dc.subjectproton transporten
dc.subjectsynthesisen
dc.subjectthermogravimetryen
dc.titleCrystal structure of monoprotonated Ni(II) nitrilotriacetate tetrahydrate [Articol]en
dc.typeArticleen

Files

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
petrenko2004.pdf
Size:
110.96 KB
Format:
Adobe Portable Document Format
Description:

License bundle

Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
1.71 KB
Format:
Item-specific license agreed upon to submission
Description:

Collections