NEW CRYSTAL FORMS OF TRIS(2-AMINOETHANOLATO-O,N)COBALT(III): STRUCTURES AND PROPERTIES
| dc.contributor.author | Cotovaia, Aliona | |
| dc.contributor.author | Șova, Sergiu | |
| dc.contributor.author | Simonov, Iurie | |
| dc.contributor.author | Roșu, Tudor | |
| dc.contributor.author | Sandu, Ion | |
| dc.contributor.author | Gulea, Aurelian | |
| dc.date.accessioned | 2023-10-25T09:31:45Z | |
| dc.date.available | 2023-10-25T09:31:45Z | |
| dc.date.issued | 2006 | |
| dc.description.abstract | Crystal forms of cobalt(III) tris(2-aminoethanolate) hydrates, i.e., red cubic crystals of the composition fac-[Co(NH2CH2CH 2O)3] • 5.44H2O (fac-I • 5.44H 2O) and blue prismatic crystals of the composition mer-[Co(NH 2CH2CH2O)3] • 3H2O (mer-I • 3H2O) were studied by the 59Co, 13C NMR and X-ray diffraction methods. It was found that mer-[Co(NH2CH2CH2O)3] • 3H 2O (mer-I • 3H2O) is a new pseudopolymorphic modification of fac-[Co(NH2CH2CH2O) 3] • 3H2O (fac-I • 3H2O), while fac-I • 3H2O represents a new polymorphic modification of the complex mer-[Co(NH2CH2CH2O)3] • 3H2O (mer-I • 3H2O) described previously. The comparative analysis of the spectra revealed dynamic equilibrium between these geometric isomers; the fac-isomer is stable in aqueous solutions. | en |
| dc.identifier.citation | COTOVAIA, Aliona, ȘOVA, Sergiu, SIMONOV, Iurie , ROȘU, Tudor, SANDU, Ion , GULEA, Aurelian. New crystal forms of tris (2-aminoethanolato-O,N)cobalt(III): Structures and propertie. În: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2006, vol. 32, pp. 841-847. ISSN 1070-3284 | en |
| dc.identifier.issn | 1070-3284 | |
| dc.identifier.uri | https://msuir.usm.md/handle/123456789/11458 | |
| dc.identifier.uri | https://doi.org/10.1134/S1070328406110121 | |
| dc.language.iso | en | en |
| dc.subject | Engineering controlled terms Chemical modification | en |
| dc.subject | crystal structure | en |
| dc.subject | Isomers | en |
| dc.subject | Nuclear Magnetic Resonance | en |
| dc.subject | Organometallics | en |
| dc.subject | X ray diffraction Engineering uncontrolled terms Comparative analysis | en |
| dc.subject | Crystal forms | en |
| dc.subject | Prismatic crystals | en |
| dc.subject | Pseudopolymorphic modification Engineering main heading Cobalt compounds | en |
| dc.title | NEW CRYSTAL FORMS OF TRIS(2-AMINOETHANOLATO-O,N)COBALT(III): STRUCTURES AND PROPERTIES | en |
| dc.type | Article | en |