SYNTHESIS AND STRUCTURE OF HETEROMETALLIC CHROMIUM(III) COMPLEXES WITH ETHYLENEDIAMINETETRAACETIC ACID

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dc.contributor.authorCiornea, Victor
dc.contributor.authorFilippova, Irina
dc.contributor.authorGulea, Aurelian
dc.contributor.authorȘova, Sergiu
dc.contributor.authorBorta, A.
dc.contributor.authorSimonov, Iurie
dc.date.accessioned2023-10-25T08:39:52Z
dc.date.available2023-10-25T08:39:52Z
dc.date.issued2005
dc.description.abstractThe complexes [M(Tsc)2][Cr(Edta)]2, where M is Ni, Cu; Tsc is thiosemicarbazide; Edta4- is the ethylenediaminetetraacetate anion, were synthesized and characterized by X-ray diffraction. The ionic structures are composed of the [M(Tsc)2] 2+ cations and [Cr(Edta)]- anions with a component ratio of 1 : 2. The cation has a distorted trans-square coordination. The carboxyl groups of the H4Edta molecule are deprotonated and the ligand is attached to the Cr atom in the hexadentate chelating mode. The cations and anions are linked by a system of hydrogen bonds.en
dc.identifier.citationCIORNEA, Victor, FILIPPOVA, Irina, GULEA, Aurelian, ȘOVA, Sergiu, BORTA, A., SIMONOV, Iurie . Synthesis and structure of heterometallic chromium(III) complexes with ethylenediaminetetraacetic acid. În: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2005, vol. 31, pp. 347-352. ISSN 1070-3284en
dc.identifier.issn1070-3284
dc.identifier.urihttps://msuir.usm.md/handle/123456789/11456
dc.identifier.urihttps://doi.org/10.1007/s11173-005-0102-6
dc.language.isoenen
dc.subjectEngineering controlled terms Charge coupled devicesen
dc.subjectcomplexationen
dc.subjectHydrogen bondsen
dc.subjectNegative ionsen
dc.subjectSuperconducting materialsen
dc.subjectSynthesis (chemical)en
dc.subjectThermal effectsen
dc.subjectX ray diffraction analysis Engineering uncontrolled terms Chromium complexesen
dc.subjectEthylenediaminetetraacetic acid (EDTA)en
dc.subjectOxide materialsen
dc.subjectWater bath Engineering main heading Chromiumen
dc.titleSYNTHESIS AND STRUCTURE OF HETEROMETALLIC CHROMIUM(III) COMPLEXES WITH ETHYLENEDIAMINETETRAACETIC ACIDen
dc.typeArticleen

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