MAGNETIC INVESTIGATION OF AN UNUSUAL DISSYMMETRIC BINUCLEAR MANGANESE CARBOXYLATE COMPLEX

dc.contributor.authorNovitchi, Ghenadie
dc.contributor.authorCostes, Jean-Pierre
dc.contributor.authorPopovschi, Lilia
dc.contributor.authorShova, Sergiu
dc.contributor.authorGulea, Aurelian
dc.date.accessioned2016-03-29T12:23:03Z
dc.date.available2016-03-29T12:23:03Z
dc.date.issued2006
dc.descriptionAffiliation: Ghenadie NOVITCHI, Institute of Chemistry, Academy of Sciences of Republic Moldova; Jean-Pierre COSTES, Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, F-31077 Toulouse Cedex, Franceen
dc.description.abstractThe magnetic susceptibility (χT) of an unusual dissymmetric binuclear manganese corboxylate complex has been measured from 2 to 300K. The magnetic data which have been fitted with help of the Heisenberg Dirac Van Vleck HDVV spin-exchange Hamiltonian HJSS=−urur, indicate that an antiferromagnetic interaction equalto J = 0.90(1) cm-1 ispresent. A correlation between J values andMn-H2O-Mn angles has been tempted.en
dc.identifier.citationNOVIȚCHI, Gh., COSTES, J-P., POPOVSCHI, L., SHOVA, S., GULEA, A. Magnetic investigation of an unusual dissymmetric binuclear manganese carboxylate complex. In: Cemistry Journal of Moldova. General, Industrial and Ecological Chemistry. 2006, nr.1, pp. 97-99en
dc.identifier.issn1857-1727
dc.identifier.urihttps://msuir.usm.md/handle/123456789/545
dc.identifier.urihttp://cjm.asm.md/taxonomy/term/11
dc.language.isoenen
dc.publisherInstitute of Chemistry of ASMen
dc.subjectmanganese(II) carboxylatesen
dc.subjectmagnetic propertiesen
dc.titleMAGNETIC INVESTIGATION OF AN UNUSUAL DISSYMMETRIC BINUCLEAR MANGANESE CARBOXYLATE COMPLEXen
dc.typeArticleen

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