SULFANILAMIDE-CONTAINING COORDINATION COMPOUNDS OF Cu (II) WITH ISATIN AND N-METHYLISATIN THIOSEMICARBAZONES
dc.contributor.author | Gulea, Aurelian | |
dc.contributor.author | Spînu, S. | |
dc.contributor.author | Țapcov, Victor | |
dc.contributor.author | Poirier, Donald | |
dc.contributor.author | Roy, Jenny | |
dc.date.accessioned | 2023-10-27T10:59:30Z | |
dc.date.available | 2023-10-27T10:59:30Z | |
dc.date.issued | 2006 | |
dc.description.abstract | Isatin (L1) and N-methylisatin (L2) β-thiosemicarbazones react in ethanol with Cu(II) chloride and bromide in the presence of sulfanilamide (Streptocid, Sf1), N′- acetylsulfanilamide (Sulfacyl, Sf2), Norsulfazole (Sf3), Aethazolum (Sf4), and Sulfadimesine (Sf5) to form coordination compounds Cu(Sf1-5)L1-2X2· nH2O (X = Cl, Br; n = 2-5). All the complexes have a monomeric structure. Thiosemicarbazones L1 and L2 in these complexes are tridentate O,N,S ligands, and sulfanilamides Sf1-5 are monodentate ligands. Thermolysis of the substances involves the steps of dehydration (70-95°C) and complete decomposition (410-530°C). | en |
dc.identifier.citation | GULEA, Aurelian, SPÎNU, S., ȚAPCOV, Victor , POIRIER, Donald, ROY, Jenny. Sulfanilamide-containing coordination compounds of Cu (II) with isatin and N-methylisatin thiosemicarbazones.În: Russian Journal of General Chemistry, 2006, vol. 76, pp. 1458-1463. ISSN 1070-3632 | en |
dc.identifier.issn | 1070-3632 | |
dc.identifier.uri | https://msuir.usm.md/handle/123456789/11490 | |
dc.identifier.uri | https://doi.org/10.1134/S1070363206090179 | |
dc.language.iso | en | en |
dc.subject | General Chemistry | en |
dc.subject | Coordination compound | en |
dc.subject | Isatin | en |
dc.subject | Thiosemicarbazones | en |
dc.subject | Sulfanilamide | en |
dc.title | SULFANILAMIDE-CONTAINING COORDINATION COMPOUNDS OF Cu (II) WITH ISATIN AND N-METHYLISATIN THIOSEMICARBAZONES | en |
dc.type | Article | en |