(Academia de Ştiinţe a Moldovei, 2013) Revenco, Mihai
The paper represents a review of the publications devoted to the studies of the infl uence of the thiosemicarbazones and their analogues coordination on the reactivity of the ligands. There are discussed the ways of activation of every atoms from the thiosemicarbazide fragment, highlighted the types of the observed reactions where the activated atoms are involved, and the new transformations, which have not been described previously. The observed effects were putted in use for elaboration of new methods of organic fi ne syntheses, for obtaining substances for biological applications, new materials including molecular magnets, catalysts, analytical reagents for determination, preconcentration and separation of metal ions.
