MATERIAL PROPERTIES OF ZINC PHTHALOCYANINE FROM FA SOLUTION AND APPLICATION IN ORGANIC SOLAR CELLS

Abstract

This paper presents for a first time asolution-processableZnPc thin films from formic acid (FA) solution by drop casting method and the photovoltaic parameters of the Organic Solar Cells (OPV) based on ZnPc-diode Schottky.Structural and optical propertiesof ZnPc thin films were investigated by X-raydiffraction (XRD),Fourier transform infrared spectroscopy (FTIR) and UV-VIS spectroscopy.XRD analysis show phase transformation of the alpha-beta phases of ZnPc thin films to beta phase due to the annealing in H 2 atmosphere at 400 o C for 30 min. FTIR analysis show that the formate ion (HCOO −) is attached to Zn(II)Pc. Further on, ITO/PEDOT: PSS/ZnPc(I 2)/Al Schottkyphotovoltaic devices with efficiency of 0.3 % were prepared and their characteristics 'enhancement is discussed. The values for the opencircuit voltage (1.03 V) and the current density (8.2 µA/cm 2) are higher than in the case of Schottky diode devices obtained by thermal vacuum evaporation.

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Keywords

Drop Casting Method, Zinc Phthalocyanine, Formic Acid, Thin Film, Organic Solar Cells

Citation

POTLOG, Tamara, FURTUNA, Vadim, RUSNAC, Roman et al. Material properties of zinc phthalocyanine from Fa solution and application in organic solar cells. In: International Journal of Industrial Electronics and Electrical Engineering. 2018, Vol. 6, Issue 1, pp. 40-46. ISSN 2347 - 6982.

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