Influența grosimii straturilor subțiri de CuO obținute prin metoda spray-piroliză asupra proprietăților electro-fizice [Articol]

Abstract

Thin copper oxide (CuO) films were obtained by the spray pyrolysis technique, with the deposition time varied between 5 and 15 minutes. The effect of thickness on the morphological, wettability, and electrical properties was investigated using atomic force microscopy (AFM), contact angle measurements, current–voltage (I–V) characteristics, resistivity, and X-ray diffraction (XRD). The results indicated an increase in roughness from 10 nm to 16 nm and in contact angle from 108° to 118° as the deposition time increased, reflecting an improvement in hydrophobicity. At the same time, an increase in electrical current and a decrease in resistivity from 3.5×10⁶ Ω·cm to 5×10⁵ Ω·cm were observed. XRD analysis confirmed the formation of the monoclinic CuO crystalline phase, demonstrating the structural stability of the films. These results indicate that deposition parameters can be adjusted to control the functional properties of the films, making them promising for electronic and optoelectronic applications.