Facultatea de Chimie şi Tehnologie Chimică / Faculty of Chemistry and Chemical Technology

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Author: search.filters.author.Gulea, AurelianSubject: search.filters.subject.bipyridine

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    Crystal structure of 4,4-bipyridine-containing complexes of copper(II) nitrate with 1-[(2-Hydroxyethylimino)methyl]naphthalen-2-ol and 2-[(2-hydroxyethylimino)methyl]phenol [Articol]
    (2009) Ciumacov, Iurie; Țapcov, Victor; Petrenko, Peter A.; Popovschi, Liliana; Simonov, Iurie; Bocelli, Gabrielle; Antoșciac, Boris; Paraschivescu, Andrei; Gulea, Aurelian
    The crystal structures of (μ-4,4-bipyridine)-di(nitrato-1-[(2- hydroxyethylimino)methyl]naphthalen-2-olocopper (I) and catena-di(μ-4,4'- bipyridine)di(μ-4,4'-bipyridine)-di(nitrato-2-[2-(hydroxyethylimino) methyl]phenolocopper)diaquacopper(II) nitrate (II) were determined. In the crystal of I, each of the two copper atoms coordinates a singly deprotonated tridentate azomethine molecule, a nitrate ion, and bipyridine, which functions as a bridge between the central atoms. The copper coordination polyhedron is a slightly distorted tetragonal pyramid with the base formed by the imine and bipyridine nitrogen atoms and the phenol and alcohol oxygen atoms. The axial site in the pyramid is occupied by the oxygen atom of the monodentate nitrate groups. In the trinuclear structure II with C2 crystal chemical symmetry, the terminal coordination unit is composed through copper coordination of monodeprotonated 2-[2-(hydroxyethylimino)methyl]phenol, bipyridine, and the nitrate anion. In the crystal, the trinuclear molecules form infinite ribbons along the z axis in which the pyridine molecules perform the bridging function. The central copper atom has an octahedral configuration formed by the nitrogen atoms of four 4,4'-bipyridine molecules and oxygen of two water molecules
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    Synthesis and physico-chemical studies of heterometallic nitrilotriacetates of chromium(III) with some 3d metals [Articol]
    (2006) Ciornea, Victor; Gulea, Aurelian
    Heterometallic complexes of chromium (III) with some 3d metals have been synthesized based on nitrilotriacetic acid (H3 nta), like M(bpy)2 Cr2 (OH)2 (nta)2·nH2O, where M = Mn 2 , Co2 , Ni 2 and Zn2 ; bpy = α,α′-bipyridine; n = 8 or 9. Their chemical composition has been determined from the results of the elemental analysis and thermogravimetric study. The coordination modes of the nta3¯ ligand and the type of chemical bonds have been proposed basing on IR spectra.
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    Synthesis and physico-chemical studies of heterometallic nitrilotriacetates of chromium(III) with some 3d metals [Articol]
    (Academia de Știinițe a Moldovei, 2006) Ciornea, Victor; Gulea, Aurelian
    Heterometallic complexes of chromium (III) with some 3d metals have been synthesized based on nitrilotriacetic acid (H3nta), like M(bpy)2Cr2(OH)2(nta)2·nH2O, where M = Mn2+, Co2+, Ni2+ and Zn2+; bp = α,α′-bipyridine; n = 8 or 9. Their chemical composition has been determined from the results of the elemental analysis and thermogravimetric study. The coordination modes of the nta3 ̄ ligand and the type of chemical bonds have been proposed basing on IR spectra.
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    Synthesis and physico-chemical studies of heterometallic nitrilotriacetates of chromium(III) with some 3d metals [Articol]
    (Institute of Chemistry of ASM, 2006) Gulea, Aurelian; Ciornea, Victor
    Heterometallic complexes of chromium (III) with some 3dmetals have been synthesized based onnitrilotriacetic acid (H3nta), like M(bpy)2Cr2(OH)2(nta)2·nH2O, where M = Mn2+, Co2+, Ni2+ and Zn2+; bpy = α,α′-bipyridine; n = 8 or 9. Their chemical composition has been determined from theresults of the elemental analysis and thermogravimetric study. The coordination modes of the nta3 ̄ ligand and the type of chemical bonds have been proposed basing on IR spectra.