Facultatea de Chimie şi Tehnologie Chimică / Faculty of Chemistry and Chemical Technology
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Item Synthesis, Structure, and Biological Activity of Mixed-Ligand Amine-Containing Copper(II) Coordination Compounds with 2-(2- Hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbothioamide [Articol](2021) Gulea, А. P.; Graur, V. О.; Ulchina, Ia. I.; Bourosh, P. N.; Smagliic, V. A.; Garbuz, O. S.; Tsapkov, V. I.Сopper(II) nitrate reacts in ethanol with 2-(2-hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbo- thioamide H2L in an 1 : 1 molar ratio to form the coordination compound Cu(HL)NO3·H 2O. The introduction of amines [imidazole (Im), 3,5-dibromopyridine (3,5-Br2Py), and 4-methylpyridine (4-Pic)] into the reaction mixture in a molar ratio 1 : 1 : 2 leads to the formation of CuA(HL)NO3·nH 2O [A = Im, 3,5-Br 2Py, 4-Pic; n = 0, 3] com- plexes. The structure of the obtained compounds was determined by X-ray structural analysis. The synthesized complexes exhibit antimicrobial, antifungal, antioxidant, and anticancer activities.