Facultatea de Chimie şi Tehnologie Chimică / Faculty of Chemistry and Chemical Technology
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Item MECANISME DE AUTOPURIFICARE CHIMICĂ A APELOR NATURALE, CU UTILIZAREA TEORIEI PROCESELOR REDOX(Editura USM, 2023) Bunduchii, Elena; Duca, GheorgheÎn lucrare sunt descrise mecanismele proceselor redox catalitice ce au loc în apele naturale, esențiale pentru procesele de autopurificare chimică. Se examinează tipurile de mecanisme redox care implică atât compuși cu transfer parțial de sarcină, radicali liberi, cât și reducători, toate întâlnite în apele naturale. Accentul este pus pe procesele redox, catalizate de ionii sau compușii complecși ai metalelor de tranziție, inclusiv cuprul, fierul și manganul. Aceste procese implică principalii agenți oxidativi din apele naturale: oxigenul (O2), peroxidul de hidrogen (H2O2) și radicalii hidroxilici (•OH).Item ASSESSMENT OF KINETIC PARAMETERS IN THE WATERS OF THE NISTRU COURSE IN THE SECTION NASLAVCEA – DUBASARI(2006) Bunduchi, Elena; Duca, Gheorghe; Gladchi, Viorica; Goreaceva, Nelli; Mardari, IgorThe current work represents the results of a monitoring executed on Nistru River waters between October 2003 and September 2005. The water quality was evaluated on the basis of such kinetic indicators as redox state and capacity of inhibition. The obtained results shows that Nistru River water in the segment Naslavcea village – Dubasari barrage are continuously polluted with reducing substances that diminish the H2O2 content, that actually determines the redox state of natural waters and the content of free radicalsItem THE STUDY OF REDOX CONDITIONS IN THE DNIESTER RIVER(2008) Gladchi, Viorica; Goreaceva, Nelli; Duca, Gheorghe; Bunduchi, Elena; Romanciuc, Lidia; Mardari, Igor; Borodaev, RuslanThe work presented in the paper discusses the contribution of the Novodnestrovsc water system to the formation of redox conditions in the lower Dniester. The conclusions were drawn on the basis of a long-term protocol of analyses that included the analysis of the oxygen regime, evaluation of the content of hydrogen peroxide,rH2, biological oxygen demand as well as other additional parameters.Item ESTIMATION OF THE NATURAL WATER SELF-PURIFICATION CAPACITY FROM THE KINETIC STANDPOINT(2008) Duca, Gheorghe; Bunduchi, Elena; Gladchi, Viorica; Romanciuc, Lidia; Goreaceva, NelliThe current paper contains a synthesis of the processes of chemical auto-purification that take place in natural waters; examples of mechanisms of such processes occurring with participation of dissolved organic matter, oxidants of the biogeochemical cycle of oxygen and of transition metals including copper and iron are presented. The kinetic indicators of natural water quality are presented as well.Item THE STUDY OF REDOX CONDITIONS IN THE DNIESTER RIVER(Academia de Știinițe a Moldovei, 2008) Gladchi, Viorica; Goreaceva, Nelli; Duca, Gheorghe; Bunduchi, Elena; Romanciuc, Lidia; Mardari, Igor; Borodaev, RuslanThe work presented in the paper discusses the contribution of the Novodnestrovsc water system to the formation of redox conditions in the lower Dniester. The conclusions were drawn on the basis of a long-term protocol of analyses that included the analysis of the oxygen regime, evaluation of the content of hydrogen peroxide, rH2, biological oxygen demand as well as other additional parameters.Item ESTIMATION OF THE NATURAL WATER SELF-PURIFICATION CAPACITY FROM THE KINETIC STANDPOINT(Academia de Știinițe a Moldovei, 2008) Duca, Gheorghe; Bunduchi, Elena; Gladchi, Viorica; Romanciuc, Lidia; Goreaceva, NelliThe current paper contains a synthesis of the processes of chemical auto-purification that take place in natural waters; examples of mechanisms of such processes occurring with participation of dissolved organic matter, oxidants of the biogeochemical cycle of oxygen and of transition metals including copper and iron are presented. The kinetic indicators of natural water quality are presented as well.Item ASSESSMENT OF KINETIC PARAME TERS IN THE WATERS OF THE NISTRU COURSE IN THE SECT ION NASLAVCEA – DUBASARI(Academia de Știinițe a Moldovei, 2006) Bunduchi, Elena; Duca, Gheorghe; Gladchi, Viorica; Goreaceva, Nelli; Mardari, IgorThe current work represents the results of a monitoring executed on Nistru River waters between October 2003 and September 2005. The water quality was valuated on the basis of such kinetic indicators as redox state and capacity of inhibition. The obtained results shows that Nistru River water in the segment Naslavcea village – Dubasari barrage are continuously polluted with reducing substances that diminish the H2O2 content, that actually determines the redox state of natural waters and the content of free radicals