(BENZOYLFORMALDEHYDE OXIMATO-j2N,O)- (BENZOYLFORMALDEHYDE OXIME-jN)- CHLORIDOPLATINUM(II)

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2007

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Abstract

In the title complex, [Pt(C 8H 6NO 2 )Cl(C 8H 7NO 2)], the Pt II centre is coordinated by a monodentate and an N,O-chelating deprotonated benzoylformaldehyde oxime and a Cl atom. There is an intramolecular N—OH—O hydrogen-bonding system between the oxime OH group and the oximate O atom.

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single-crystal X-ray study, T = 100 K, mean (C–C) = 0.006 A˚, R factor = 0.022, wR factor = 0.043, data-to-parameter ratio = 12.9

Citation

CUCUȘCHIN, Nikolae; Petru CHETRUȘ și Matti HAUKKA. (Benzoyl-formaldehyde oximato-κ2 N,O)(benzoyl-formaldehyde oxime-κN) chloridoplatinum(II). Acta Crystallographica Section E: Structure Reports Online. 2007, vol. 63, pp. 1-8. ISSN 1600-5368.

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