SPONTANEOUS SYMMETRY BREAKING AS A LAW OF NATURE
Date
2023
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Abstract
In a semi-review paper, it was discussed the notion of symmetry of polyatomic systems defined
as invariance under transformations, and show that this important property of atomic matter is extremely
vulnerable, and may undergo internal breakdown, subject to the presence of electronic degeneracy or
pseudodegeneracy. First formulated by Landau, L. in 1934, later proved and published by Jahn and Teller,
this Jahn-Teller effect (JTE) underwent tremendous developments with important applications in physics,
chemistry, biology, and materials science. Less attention was paid to the roots of this phenomenon and
its correct interpretation in the sense of its influence on observable properties. It is shown that electronic
degeneracy and its extended form, called pseudodegeneracy, are actually the only source of spontaneous
symmetry breaking (SSB) in nature, including all forms of matter, beginning with elementary particles,
via nuclei, atoms, molecules, and solids. Theoretically, the vulnerability of the notion of symmetry is due
to the fact that, following quantum mechanics, the separation of the motion of electrons and nuclei
(and, similarly, the separation of motions of elementary particles) is approximate, and hence the classical
notion of polyatomic space configuration is approximate too, with SSB as one of its main violation.
Description
Keywords
adiabatic potential, electronic degeneracy, Jahn-Teller effect
Citation
BERSUKER, Isaac. Spontaneous symmetry breaking as a law of nature. In: Chemistry Journal of Moldova, 2023, nr. 2(18), pp. 7-14. ISSN 1857-1727.