Solvothermal synthesis, crystal structure and photoluminiscence of Cd(II) coordination polymer derived from a 1,2,3-triazole-based tricarboxylate ligand [Articol]

dc.contributor.authorGorinchoy, Viorinaen
dc.contributor.authorShova, Sergiuen
dc.contributor.authorKulikova, Olgaen
dc.contributor.authorRoman, Gheorgheen
dc.contributor.authorLozan, Vasileen
dc.date.accessioned2026-02-18T08:51:31Z
dc.date.issued2025
dc.description.abstractA new polymeric complex of cadmium(II) was synthesized under solvothermal conditions by the reaction of 5-(4-carboxy-5-methyl-1H-1,2,3-triazol-1-yl) isophthalic acid (H3L) with cadmium nitrate tetrahydrate in a mixture of N,N-dimethylacetamide and water. The obtained compound was investigated using single crystal X-ray diffraction, thermogravimetry, infrared and photoluminescence spectroscopies. The polymeric complex obtained is an infinite 2D coordination polymer with the general formula {[Cd3L2(H2O)6]·2H2O}n (1). The intense photoluminescence emission of cadmium (II) complex was observed in the blue-violet region of the spectrum.en
dc.description.sponsorshipThis work was supported by Subprogram 010602 „Synthesis and study of new materials based on coordination compounds with polyfunctional ligands and with useful properties in medicine, biology and technology”, Institute of Chemistry, Moldova State University.en
dc.identifier.citationGORINCHOY, Viorina; Sergiu SHOVA; Olga KULIKOVA; Gheorghe ROMAN and Vasile LOZAN. Solvothermal synthesis, crystal structure and photoluminiscence of Cd(II) coordination polymer derived from a 1,2,3-triazole-based tricarboxylate ligand. Chemistry Journal of Moldova. General, industrial and ecological chemistry. 2025, nr.20(2), pp. 25-32. ISSN 1857-1727 (p), ISSN 2345-1688 (e). Disponibil: https://doi.org/10.19261/cjm.2025.1389en
dc.identifier.issn1857-1727 (p)
dc.identifier.issn2345-1688 (e)
dc.identifier.urihttps://msuir.usm.md/handle/123456789/20240
dc.identifier.urihttps://doi.org/10.19261/cjm.2025.1389
dc.language.isoen
dc.subjectcoordination polymeren
dc.subject1en
dc.subject2en
dc.subject3-triazoleen
dc.subjectthermogravimetryen
dc.subjectphotoluminescenceen
dc.titleSolvothermal synthesis, crystal structure and photoluminiscence of Cd(II) coordination polymer derived from a 1,2,3-triazole-based tricarboxylate ligand [Articol]en
dc.typeArticle

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