Browsing by Author "Cazac, Tatiana"

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    ADSORPTION WAVE OF VAN ADIUM COMPLEX WITH 2,3–DIHYDROXYBE NZALDEHYDE
    (Academia de Știinițe a Moldovei, 2009) Kiriyak, Ludmila; Cecoi, Natalia; Cazac, Tatiana; Revenco, Mihail
    The polarographic behavior of the complex formed by V(V) and 2,3–ihydroxybenzaldehyde (2,3–DHBA) in the solution containing acetate buffer (pH 5,2) has been investigated. By means of a.c. polaro-graphy, chronovoltammetry and other techniques, it has been shown that the electrode process is complicated by the adsorption of 2,3-DHBA and its vanadium complex. The kinetic and adsorption parameters of the electrode process have been determined: adsorption equilibrium constant B= 1,32⋅105 mol-1⋅dm3, the attraction constant γ = 1,2, the maximum surface concentration Гmax = 9,10⋅10-11 mol⋅ cm-2; the share of the electrode surface occupied by one particle of the adsorbed complex S = 1,81 nm2 and the free adsorption energy ∆G = - 39,1 kJ· mol-1.
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    ADSORPTION WAVE OF VANADIUM COMPLEX WITH 2,3–DIHYDROXYBENZALDEHYDE
    (Institute of Chemistry of ASM, 2009) Kiriyak, Ludmila; Cecoi, Natalia; Cazac, Tatiana; Revenco, Mihail
    The polarographic behavior of the complex form ed by V(V) and 2,3–dihydroxybenzaldehyde (2,3–DHBA) in the solution containing acetate buffer (pH 5,2) has been investigated. By means of a.c. polarography, chronovoltammetry and other techniques, it has been shown that the electrode process is complicated by the adsorption of 2,3-DHBA and its vanadium complex. Th e kinetic and adsorption para meters of the electrode process have been determined: adso rption equilibrium constant B= 1,32⋅105 mol-1⋅dm3, the attraction constant γ = 1,2, the maximum surface concentration Гmax = 9,10 ⋅10-11 mol⋅ cm-2; the share of the electrode surface occupied by one particle of the adsorbed complex S = 1,81 nm2 and the free adsorption energy ∆G = - 39,1 kJ· mol-1.
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    ELECTROCHEMICAL BEHAVIOUR OF THE LEAD IN THE PRESENCE OF THE PIRUVIC ACID THIOSEMICARBAZONE
    (Academia de Ştiinţe a Moldovei, 2006) Cazac, Tatiana; Revenco, Mihail
    Continuing our efforts to ind new organic agents for adsorptive accumulation of the toxic metal ions on the mercury dropping electrode, allowing to reduce signiicantly the detection limits, we present here the results of investigation of the electrochemical behavior of the lead ions in the presence of the piruvic acid thiosemicarbazone, APTSC ( see ig.). In water solutions Pb(II) forms in presence of the piruvic acid thiosemicarbazone a complex of the molar ratio Pb:L = 1:2, conirmed by amperometric titration, which one is easily adsorpted on the mercury electrode. On the voltamogramme of the water solutions in the pH range 5-6 the reduction peak of the adsorpted species is observed at the potential -0,5 V. Adsorptive nature of this peak is conirmed by the value of the rate coeficient and by variation of the dropping time with applied potential in separate solutions and their mixtures (see ig.). Interferences of the Zn(II), Cd(II), Ni(II), Co(II), Cl-, Br-, I- CNS-, CH COO-, etc. ions have been investigated and optimized for the maximal manifestation of the Pb(II) signal. The optimal potential for accumulation of the lead ions from solution containing the given thiosemicarbazone is -0,15 V. The maximal admitted time for accumulation is 3 min. For the linear cathodic scanning of the potential (1 V/s), the function Ip=f(CM) is linear in conditions of stationary diffusion and dropping mercury electrode up to the concentration of the lead 2⋅10-6 M. Using the accumulation of the lead species during 180 s on the stationary mercury drop the detection limit diminished to the 3⋅10-8 M. Smaller detection limits should be reached increasing the surface of mercury drops. The main parameters of the adsorption, such as adsorption constant, particles transfer coefficients, free adsorption energy, maximal concentration on the interface, as well as the surface corresponding to one adsorbed particle on the electrode, were determined. Analytical potentialities of the investigated phenomenon for determination of small lead concentration were evaluated.figureFig. Variation of the dropping time with applied potential in solutions of 1) 0.01 M KCl; 2) 0.01 M KCl + 5·10-5 M APTSC 3) 0.01 M KCl+5·10-5M APTSC + 5·10-5 M Pb2.
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    SYNTHESIS, STRUCTURE AND SPECTROPHOTOMETRIC PROPERTIES OF PALLADIUM(II) 8-QUINOLINALDEHYDE N(4)-(2,4,6)- TRIMETHYLPHENYLTHIOSEMICARBAZONE
    (Academia de Ştiinţe a Moldovei, 2015) Bulmaga, Petru; Bourosh, Pavlina; Sirbu, Ana; Corja, Ion; Cazac, Tatiana