Баранов, С.А.2024-03-262024-03-262024БАРАНОВ, С.А. Нуклеация наночастиц в электрохимии. In: Integrare prin cercetare și inovare: conferința științifică națională cu participare internațională. Ştiinţe ale naturii și exacte, 9-10 noiembrie 2023. CEP USM, 2024, pp. 636-644. ISBN 978-9975-62-690-3.978-9975-62-690-3https://msuir.usm.md/handle/123456789/14627БАРАНОВ, С.А. Нуклеация наночастиц в электрохимии. In: Integrare prin cercetare și inovare: conferința științifică națională cu participare internațională. Ştiinţe ale naturii și exacte, 9-10 noiembrie 2023. CEP USM, 2024, pp. 636-644. ISBN 978-9975-62-690-3.It is shown that the earlier discovered features of the composition and properties of electrochemical coatings obtained by the induced codeposition from alloys of iron-group metals (W, Mo, Re)—such as nanocrystallinity (X-ray amorphism), macroscopic dimensional effects of microhardness and corrosion resistance, the effect of the volume current density on the properties and composition—are a consequence of the fractality of the solutions of complexes (citrate, gluconate, etc.) in combination with the intensive interfacial exchange. In this case, the kinetics of nano-nucleation limits the size of the resulting alloy nucleus, as a result of which water molecules participate in the formation of coatings, leading to the incorporation of oxidehydroxide inclusions into the solid phase and hydrogenation.ruндуцированное соосаждениесплавы с тугоплавкими металламиArticle