Samusi, NinaStrelcov, EugeniuȚapcov, VictorGulea, Aurelian2023-10-242023-10-242004SAMUSI, Nina, STRELCOV, Eugeniu, ȚAPCOV, Victor , GULEA, Aurelian. Lanthanide complexes with N,N′-Bis(2-hydroxybenzylidene)-2- hydroxyphenylmethanediamine. În: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2004, vol. 30, pp. 275-279. ISSN 1070-32841070-3284https://msuir.usm.md/handle/123456789/11445https://doi.org/10.1023/B:RUCO.0000022803.79964.5fComplexes of lanthanides with N,N′-bis(2-hydroxybenzylidene)-2- hydroxyphenylmethanediamine (H3L) were synthesized and investigated by the elemental, IR, magnetochemical, and thermogravimetric methods. Using the data obtained, they were found to have compositions Ln2L 2·nH2O and La2L2· MCl2·4H2O (Ln = La3+, Pr3+, Nd3+, Dy3+, Er3+; M = Cu2+, Co 2+, Ni2+; n = 4, 6). Suggestions on their structures were made. In the interval of 20-140°C, these complexes were shown to be high-resistance semiconductors.enEMTREE drug terms benzylidene derivativeDysprosiumErbiumlanthanidelanthanumneodymiumpraseodymium EMTREE medical terms articlechemical structureinfrared spectroscopymagnetismsemiconductorsynthesisthermogravimetryArticle